Jackie had been busy staring at the bad guy and all of his toys...and trying to not look like she's got a knife behind her back. When Chuck looks over, she mentally facepalms and starts trying to rub it against his ropes unobtrusively. She gives Chuck a "com'n, keep him busy!" look as she works.

The kidnapper lights a cigarette to start, letting out a cloud of smoke at them. Where is the painting? As if this is the last time he's going to ask nicely.